City College Interns in Materials Research 1999

Intern: Aaron Pfannestiel

Mentor: Antonio Santos

Faculty Sponsor: Dr. Tony Cheetham

Supporting Grant Agency: Materials Research Lab

Academic Major: Geology

Project Title: "The Synthesis and Characterization of Bismuth Manganese Perovskites"

Abstract:  Bismuth Manganese Perovskites have extraordinary mechanical, magnetic and electrical properties. At low temperatures this perovskite is both ferromagnetic and ferroelectric. This unusual behaviorcould lead to enhanced device performance, to date these properties are not fully understood and application has not been fully examined.
Most syntheses of this type of perovskite normally occur under great pressure and high temperatures. We however focused on alternative methods of synthesis. Our synthesis required putting the precursors into solution and then attempting to crystallize a perovskite out of that solution. A process of many cycles of heat treatment at different temperatures was utilized in hopes that we would find a certain temperature that the perovskite favored. We also enlisted the use of thin films in hopes that we would be able to grow a Perovskite on a substrate. This process involved deposition of a minute amount of our solution on either a Lanthanum Aluminum or Strontium Titanium substrate.
X-ray diffraction allowed us to characterize the powders and thin films we were producing in the lab. We were also able to see the evolution that took place during the heat treatment process with X-ray diffraction.


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